Dr.k.k.saravanan
Ru-dye grafted cus and reduced graphene oxide (cus/rgo)composite:an efficient and photo tunable electrode for dye sensitized solar cells
- Authors Details :
- K. K. Saravanan P. Sivakarthik
Journal title : Journal of Cluster Science
Publisher : Springer Science and Business Media LLC
Online ISSN : 1572-8862
Page Number : 401-407
Journal volume : 31
Journal issue : 2
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Original Article
The CuS@reduced graphene oxide (CuS/RGO) hybrid nanocomposite was synthesized by facile hydrothermal method and
used as a photoelectrode material in photovoltaic applications. In the hydrothermal route, RGO is formed by the reduction
of GO with simultaneous formation of CuS/RGO nanocomposites. The CuS/RGO nanocomposites was investigated using
powder XRD, TEM, HR-TEM, Raman, XPS, DRS UV–Vis spectroscopy, Photoluminescence (PL) measurements. XRD
and TEM results suggest that CuS crystalline with individual spherical like homogeneous nanoparticles sizes in the range
of 45–35 nm, which is distributed throughout the RGO sheets. We further construct the flexible photoelectrodes by using
CuS and RGO and studied the photovoltaic performance. Photovoltaic parameters, such as short-circuit photocurrent
density, open circuit voltage, fill factor and conversion efficiency were found to be 16 mA/cm2
, 0.71 V, 70.1% and 7.81%
respectively, for CuS/RGO photoelectrode. The improved photo conversion efficiency of CuS/RGO is due to enhancing the
electronic injection ability and reducing the photogenerated charge recombination. These photovoltaic results indicate a
simple methodology for the low cost and effortless synthesis of an alternative CuS/RGO photoelectrode in high performance photovoltaic devices.
Article DOI & Crossmark Data
DOI : https://doi.org/10.1007/s10876-019-01653-1
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